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Another weird thing is that when I export the database and import it locally (using … nitrite, dissolved N2, and ammonium from the definition of & The calculation finds the thermodynamically most stable assemblage. Aragonite and Calcite are both CaCO3. Both may be supersaturated in a solution, but PHREEQC will usually precipitate calcite because when it is in equilibrium with calcite the solution is usually undersaturated with aragonite. Overview of PHREEQC Version 3. Sources/Usage...